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50   TECHNOLOGY                                                                   SEP/OCT 2024 FDM ASIA | www.fdmasia.com






                                                                In this context, Zhang and co-workers produced a highly
                                                             transparent wood composite (optical transmittance beyond
                                                             83%) derived from delignified balsa wood.
                                                                This latter was infiltrated with refractive-index-matched

                                                             partially polymerised acrylamide, in the presence of very small
                                                             amounts of nanofiller, namely: Ag nanowires (0.1 wt%), carbon
                                                             nanotubes (0.1 wt%), and reduced graphene oxide (0.1 wt%).
                                                                The resulting TW composite exhibited a very low
                                                             thermal conductivity (around 0.45 W/(mK)) and a remarkable
                                                             electromagnetic absorption performance. In particular, for
                                                             2.0 mm thick samples, the effective absorption bandwidth
                                                             achieved 9.5 GHz, almost seizing the whole X (8.2–12.4 GHz)
                                                             and Ku (12.4–18 GHz) bands.



                                                             Perspectives
            Zhou et al. thoroughly investigated the performance of a   The idea of creating transparent wood was born to study the
          fully biobased, biodegradable, and flexible transparent wood,   anatomical characteristics  of the wood itself. However, the
          suitable for replacing traditional plastics in flexible electronics,   growing awareness of energy saving, the need to create a
          anti-counterfeiting, and UV protection applications.   virtuous system based on the recyclability of materials and the
            To this aim, gelatine was grafted onto delignified balsa   circular economy, and the urgent demand for limiting global

          wood and subsequently crosslinked with tannic acid: the so-  warming have recently proposed TW as one of the possible
          obtained films (thickness of about 100 μm) combined high   answers to these problems.
          tensile strength (around 155 MPa) and optical transmittance   The possibility of creating windows that would allow light
          (86.2% at 600 nm), low haze and UV blocking effectiveness,   to pass through but which, at the same time, would act as a
          as well as remarkable stability in water.          thermal barrier, immediately appeared as an obvious but essential
            Liu and co-workers succeeded in preparing transparent   application of TW. In addition, the advantage represented
          wood (from balsa wood) with soft-/hard-switchable and shape   by the enhanced impact resistance properties compared to
          recovery capabilities by infiltrating an epoxy-based polymer   traditional glass has made it a potential replacement for both
          (whose Tg – glass transition temperature – was around 0°C)   practical and commercial interest.

          into the delignified wood template. The resulting material   On the other hand, even the material obtained when the
          showed high optical transparency and haze (70 and 95%,   internal structure of the wood remains visible soon aroused the
          respectively, for TW samples 2.0 mm thick), tunable stiffness,   economic interest of furniture manufacturers, who immediately
          and shape-recovery capability.                     appreciated its aesthetic characteristics.
            One very recent application of transparent wood refers   At present, the growing interest in this material is beginning
          to the design of effective electromagnetic wave absorption   to involve more advanced sectors, in particular electronics:
          materials characterised by small thickness and wide effective   indeed, TW is proving to be an appealing material in the

          absorption bandwidth, which may contribute to alleviating   fields of solar cells, luminescent devices, photonics, and
          electromagnetic pollution.                         LEDs, among others.
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