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40   TECHNOLOGY                                                                   SEP/OCT 2024 FDM ASIA | www.fdmasia.com






         Flickr                                              varying compositions of the coatings used. White paint, which
                                                             contains a filler, likely contributes to the increased bulk density.


                                                             Relative Hardness and Density Profile

                                                             The surface with clear varnish exhibited a higher relative
                                                             hardness of 0.15, whereas the surface coated with white
                                                             varnish had a relative hardness of 0.11. This information is
                                                             crucial when considering the fractional composition of the
                                                             particles after milling.
                                                                More complex coatings tend to be more brittle, which
                                                             can increase the proportion of smaller fractions, specifically
            For industrial particles, most fractions fall within the 1–4   those less than two mm, or even dust. The values obtained
          mm range. In contrast, particles obtained from reclaimed   are consistent with other studies.

          wood window frames are reduced during shredding, with   Another study investigated the effect of temperature on
          most fractions ranging from 0.25–4 mm, particularly for those   various coatings (varnishes were applied to the heated wood),
          with white paint.                                  including cellulose lacquer, synthetic varnish, polyurethane
            A similar trend is observed with particles from clear   varnish, and water-based varnish.
          varnish-painted window frames; however, these contain a   The initial heat treatment of the wood did not contribute
          higher proportion of fine fractions than white-painted particles.   to the relative hardness of the varnishes used.
            The higher density and brittleness of varnishes compared   Varnished wooden surfaces are exposed to various external

          to wood likely contribute to the shortening of the particles. A   variables depending on their application. To avoid economic
          similar trend of particle shortening was observed in studies   loss,  it  is critical  to  select varnishes that provide  optimal
          where particleboards were subjected to repeated milling.   performance matched to the specific area of application.
            These particleboards contained laminate, which has a high   Studies report that the enrichment of the varnish with TiO2
          density similar to varnish. Additionally, the adhesive content   and Al2O3 nanofillers promotes a reduction in the thickness
          increased with each successive batch of particleboard made   of the surface layer and thus contributes to the hardness of
          from particleboard residues.                       the coating and the ability to absorb UV radiation.
            Once cured, this adhesive also has a higher density than   The relative hardness for the clear varnish and the white
          wood. Consequently, there was a significant shortening of wood   paint used in the tests was shown. The density profile of the

          fibres, as confirmed by the studies of Wronka and Kowaluk.  white paint, which has a lower density and does not penetrate
            The industrial particles, free from contamination, recorded   the wood as deeply as the clear varnish (orange line), which
          the lowest bulk density (145 kg m−3).              may be due to the presence of fillers in the paint.
            The blue bar represents the bulk density values of window   The lack of fillers in the paint makes the paint penetrate
          frame mill particles painted with clear paint (177 kg m−3). This   the wood better, which can affect some test results, such as
          value is higher than industrial particles but lower than the bulk   water absorption or bulk density.
          density of particles from milled window frames painted with   Paint layer thickness can vary greatly depending on solvent

          white paint (192 kg m−3).                          evaporation, surface tension gradients, and paint application
            The differences in these values may be attributed to the   processes, and also, the temperature of the liquid top coating
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