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40   TECHNOLOGY                                                                    JAN/FEB 2025 FDM ASIA | www.fdmasia.com






         Андрей Перцев 1967                                  unique features characteristic of other materials.
                                                                Łukawski et al. showed that graphene wood surfaces can
                                                             meet the conditions characteristic of electronic requirements.
                                                                Graphene materials can also give wood superhydrophobic

                                                             and anti-corrosion properties. However, the durability of the
                                                             newly acquired features is of great importance.
                                                                In order to better understand these features, an in-depth
                                                             analysis of the structural changes that occur in wood due
                                                             to modification with graphene oxide should be carried out.
                                                                In this work, the LIBS method was used to determine the
                                                             elements, mainly carbon, and to characterise the differences
                                                             in the elemental composition between the surface layers of
          is used to modify the surface layers. The way graphene oxide   wood impregnated with graphene oxide and native wood.

          penetrates the anatomical structures of wood may differ from   This study aimed to determine whether carbon from
          how substances not in the nanoscale penetrate.     graphene oxide is incorporated into the surface layers of
            Moreover, the way chemicals penetrate wood depends on   wood tissue. Identification of this phenomenon was possible
          the moisture content of the wood and the chemical nature   thanks to appropriately selected method parameters, which
          of a given substance.                              enabled the detection of intermediate layers between the
            Undoubtedly, the anatomical structure of wood influences   graphene oxide layer and the native material.
          the way chemicals penetrate and are located in wood.   In order to confirm the validity of the conclusions, studies

            Further, the methods and the parameters selected for   were performed using FTIR spectrometry, which confirmed the
          introducing chemical substances have a great significance   occurrence of changes in the structure of polymers building
          on the quality of impregnated wood. The action of vacuum   the wood tissue and an increase in cellulose crystallinity.
          conditions and ultrasound can cause different interactions of
          chemical substances with wood cells.               Materials and Techniques Used During the Research
            In order for graphene oxide to become a commonly used   Analysis
          material for wood modification in the future, it is necessary to   Pine (Pinus sylvestris L.) samples with dimensions of 40 × 40
          first learn about the interactions in the wood structure and the   × 4 mm were used for the tests. Wood sapwood was used
          most  effective  ways  of  introducing  it  into  the  wood  in  such   for the tests. Wood density at 12 percent moisture content

          a way as to obtain a composite with the desired properties.  was 600 kg/m3.
            The studies provided valuable information on the structural   A water dispersion of graphene oxide (Advanced Graphene
          phenomena occurring during wood modification with graphene   Products S.A., Zielona Góra, Poland) was used to impregnate
          oxide.                                             wood, diluted with water, to obtain a solution with a concentration
            Wood is a unique technical and technological material that   of 0.08 percent.
          can be modified to improve its properties. However, there are   The diameter of the graphene oxide flake was 500–1000
          few reports on using graphene oxide for wood modification.   nm. The graphene oxide suspension in water was stirred for

            At the same time, the few works that have been published   15 min using PS-40A ultrasound to reduce the aggregating
          indicate that graphene oxide and its derivatives can give wood   graphene oxide flakes in the solution.
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